DIRECT OBSERVATION OF ELECTRON LOCALIZATION IN A MIXED-VALENCE DOUBLE SALT - A POLARIZED NEUTRON-DIFFRACTION STUDY OF K3(MNO4)2

被引：6

作者：

CANNON, RD ^{[3
]}

JAYASOORIYA, UA

ANSON, CE

WHITE, RP

TASSET, F

BALLOU, R

ROSSEINSKY, DR

机构：

[1] LAB LOUIS NEEL,CNRS,F-38042 GRENOBLE,FRANCE

[2] INST MAX VON LAUE PAUL LANGEVIN,F-38042 GRENOBLE,FRANCE

[3] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 19期

关键词：

D O I：

10.1039/c39920001445

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polarised neutron diffraction study of the compound K3(MnO4)2 shows strong localisation of the unpaired electrons on half of the manganese sites, confirming the formulation as a mixed-valence double salt K3[MnVIIO4][MnVIO4].

引用

页码：1445 / 1446

页数：2

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