RBFE(HPO4)2 - AN IRON(III) PHOSPHATE WITH AN INTERSECTING TUNNEL STRUCTURE

被引：15

作者：

LII, KH ^{[1
]}

WU, LS ^{[1
]}

机构：

[1] NATL CHUNGHSING UNIV,DEPT CHEM,TAICHUNG,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 10期

关键词：

D O I：

10.1039/dt9940001577

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new iron(III) phosphate, RbFe(HPO4)2, has been synthesised hydrothermally at 230-degrees-C and characterized by single-crystal X-ray diffraction. The crystal is trigonal with a very long c axis: space group R3cBAR, a = 8.160(1), c = 52.75(1) angstrom, z = 18 and R = 0.0207. The compound adopts an intersecting tunnel structure, with the rubidium cations in the tunnels. The framework consists of corner-sharing FeO6 octahedra and HPO4 groups. A triclinic polymorph was also obtained.

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页码：1577 / 1580

页数：4

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