UNCONVENTIONAL RADICAL POLYMERIZATIONS

被引：40

作者：

SIMIONESCU, CI

SIMIONESCU, BC

机构：

[1] Polytechnic Inst of Jassy, Dep of, Organic & Macromolecular, Chemistry, Iasi, Rom, Polytechnic Inst of Jassy, Dep of Organic & Macromolecular Chemistry, Iasi, Rom

来源：

PURE AND APPLIED CHEMISTRY | 1984年 / 56卷 / 03期

关键词：

PLASMAS - Applications - POLYMETHYL METHACRYLATE;

D O I：

10.1351/pac198456030427

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper deals with unconventional radical polymerizations (copolymerizations) not described by the classical kinetic model. Plasma-induced polymerization is presented as an example of free radical polymerization with instantaneous initiation and without termination. This new approach to polymer synthesis is proven to proceed through a living radical mechanism and to yield ultrahigh molecular weight polymers with narrow polydispersity.

引用

页码：427 / 438

页数：12

共 44 条

[1] THE MECHANISM OF FREE RADICAL POLYMERIZATION IN THE SOLID STATE [J].

ADLER, G ;

BALLANTINE, D ;

BAYSAL, B .

JOURNAL OF POLYMER SCIENCE, 1960, 48 (150) :195-206

[2] KINETICS OF FREE RADICAL POLYMERIZATION UNDER CONDITIONS OF DIFFUSION-CONTROLLED TERMINATION [J].

BENSON, SW ;

NORTH, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (06) :935-&

[3] MONODISPERSE POLYSTYRENE [J].

BIANCHI, JP ;

PRICE, FP ;

ZIMM, BH .

JOURNAL OF POLYMER SCIENCE, 1957, 25 (108) :27-38

[4] AUTO-ACCELERATION IN FREE-RADICAL POLYMERIZATIONS CAUSED BY ORIENTED MONOMER-POLYMER ASSOCIATION COMPLEXES [J].

CHAPIRO, A .

PURE AND APPLIED CHEMISTRY, 1981, 53 (03) :643-655

[5] STEREOREGULAR BLOCK COPOLYMERS OBTAINED BY A RADICAL PROCESS IN INCLUSION COMPOUNDS [J].

FARINA, M ;

DISILVESTRO, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (21) :842-843

[6] STUDY OF KINETIC REGULARITIES AND MECHANISM OF METHYL-METHACRYLATE RADICAL POLYMERIZATION IN PRESENCE OF ORTHO-PHOSPHORIC ACID [J].

GARINA, ES ;

OLENIN, AV ;

ZUBOV, VP ;

KUCHANOV, SI ;

POVOLOTSKAYA, ES ;

KABANOV, VA .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1978, 16 (09) :2199-2215

[7]

GARINA ES, 1976, VYSOKOMOL SOEDIN B, V18, P287

[8]

HORIE K, 1974, MAKROMOL CHEM, V175, P2091

[9]

INOUE T, 1977, 26TH INT C PUR APPL, P1438

[10]

IOAN S, 1981, POLYM BULL, V5, P563, DOI 10.1007/BF00254365

← 1 2 3 4 5 →