HETEROCYCLES AS LIGANDS .16. (2,5-C4TBU2RHN)MCL3 (M = TI, ZR, HF) R = H, SIME3) - AZACYCLOPENTADINYL COMPLEXES OF GROUP-4 METALS

被引：29

作者：

KUHN, N ^{[1
]}

STUBENRAUCH, S ^{[1
]}

BOESE, R ^{[1
]}

BLASER, D ^{[1
]}

机构：

[1] UNIV GESAMTHSCH ESSEN,INST ANORGAN CHEM,W-4300 ESSEN 1,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 440卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80207-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The azacyclopentadienyl compounds (2,5-C4tBu2RHN)MCl3 (M = Ti, Zr, Hf; R = H, SiMe3) have been prepared as stable solids from the lithiated pyrroles and MCl4. The pi-coordination of the azacyclopentadienyl ligands, as suggested from C-13 NMR data, has been confirmed for (2,5-C4tBu2H2N)TiCl3 by an X-ray diffraction study.

引用

页码：289 / 296

页数：8

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