SOLVATION DYNAMICS OF LDS 750 IN ASSOCIATIVE LIQUIDS BY DEGENERATE 4-WAVE-MIXING AND TIME-RESOLVED EMISSION TECHNIQUES

被引：29

作者：

GOLDBERG, SY

BART, E

MELTSIN, A

FAINBERG, BD

HUPPERT, D

机构：

[1] Raymond and Beverly Sackler of Exact Sciences, School of Chemistry, Tel-Aviv University, Tel-Aviv

来源：

CHEMICAL PHYSICS | 1994年 / 183卷 / 2-3期

关键词：

D O I：

10.1016/0301-0104(90)00097-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We developed theoretically and experimentally the principles of a spectroscopical method based on resonance transient population gratings for a quantitative description of solvation dynamics of large molecules in liquid solutions. The solvation dynamics of LDS 750 in methanol, 1,2-ethanediol, 1,3-propanediol and 1,4-butanediol have been measured over four time decades from 100 fs to 1000 ps. The solvation dynamics of LDS 750 in all solvents consists of ultrafast as well as slow components.

引用

页码：217 / 233

页数：17

共 81 条

[1] GENERALIZED LANGEVIN EQUATION APPROACH FOR ATOM-SOLID-SURFACE SCATTERING - GENERAL FORMULATION FOR CLASSICAL SCATTERING OFF HARMONIC SOLIDS [J].