METAL CATION - GLUCOPYRANOSIDE COTRANSPORT THROUGH A LIQUID ORGANIC MEMBRANE

被引：26

作者：

PAUGAM, MF ^{[1
]}

MORIN, GT ^{[1
]}

SMITH, BD ^{[1
]}

机构：

[1] UNIV NOTRE DAME,DEPT CHEM & BIOCHEM,NOTRE DAME,IN 46556

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 49期

关键词：

ACTIVE TRANSPORT; GLUCOPYRANOSIDE; PHENYLBORONIC ACID; IONOPHORE; LIQUID ORGANIC MEMBRANE;

D O I：

10.1016/S0040-4039(00)61490-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A carrier admixture of phenylboronic acid and ionophore (cryptand or crown ether) simultaneously cotransports p-nitrophenyl beta-glucopyranoside, M(+) and OH- through a liquid organic membrane. The transport mechanism involves the apparent self-assembly of a lipophilic ion-pair, comprising of anionic, phenylboronate-glucopyranoside adduct and metal cation-ionophore complex. Active glucopyranoside transport (i.e. uphill transport against a concentration gradient) was achieved in the direction of a metal cation concentration gradient.

引用

页码：7841 / 7844

页数：4

共 18 条

[1]

Alberts B. D., 1989, MOL BIOL CELL, P301

[2]

Araki T., 1990, LIQUID MEMBRANES CHE

[3] A B-11 AND C-13 NMR DETERMINATION OF THE STRUCTURES OF BORATE COMPLEXES OF PENTOSES AND RELATED SUGARS [J].

CHAPELLE, S ;

VERCHERE, JF .

TETRAHEDRON, 1988, 44 (14) :4469-4482

[4]

Ferrier RJ, 1978, ADV CARBOHYD CHEM BI, V35, P31

[5] C-13 MAGNETIC-RESONANCE SPECTROSCOPIC EVIDENCE FOR FORMATION OF BORATE COMPLEXES OF POLYHYDROXY COMPOUNDS [J].

GORIN, PAJ ;

MAZUREK, M .

CARBOHYDRATE RESEARCH, 1973, 27 (02) :325-339

[6] C-13 RESONANCE SPECTROSCOPIC STUDIES ON FORMATION OF BORATE AND DIPHENYLBORINATE COMPLEXES OF POLYHYDROXY COMPOUNDS [J].

GORIN, PAJ ;

MAZUREK, M .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1973, 51 (19) :3277-3286

[7] SELECTIVE TRANSPORT OF RIBONUCLEOSIDES THROUGH A LIQUID MEMBRANE [J].

GROTJOHN, BF ;

CZARNIK, AW .

TETRAHEDRON LETTERS, 1989, 30 (18) :2325-2328

[8] THE RELATIONSHIP BETWEEN COMPLEX STABILITY-CONSTANTS AND RATES OF CATION-TRANSPORT THROUGH LIQUID MEMBRANES BY MACROCYCLIC CARRIERS [J].

LAMB, JD ;

CHRISTENSEN, JJ ;

OSCARSON, JL ;

NIELSEN, BL ;

ASAY, BW ;

IZATT, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (22) :6820-6824

[9] RIBONUCLEOSIDE MEMBRANE-TRANSPORT BY A NEW CLASS OF SYNTHETIC CARRIER [J].

MOHLER, LK ;

CZARNIK, AW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (07) :2998-2999

[10] ALPHA-AMINO-ACID CHELATIVE COMPLEXATION BY AN ARYLBORONIC ACID [J].

MOHLER, LK ;

CZARNIK, AW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (15) :7037-7038

← 1 2 →