PRACTICAL ASYMMETRIC VERSION OF THE INTERMOLECULAR PAUSON-KHAND REACTION

被引：46

作者：

BERNARDES, V

VERDAGUER, X

KARDOS, N

RIERA, A

MOYANO, A

PERICAS, MA

GREENE, AE

机构：

[1] UNIV BARCELONA,DEPT QUIM ORGAN,E-08028 BARCELONA,SPAIN

[2] UNIV J FOURIER,LEDSS,F-38041 GRENOBLE,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)75842-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first practical asymmetric version of the intermolecular Pauson-Khand reaction has been developed based on novel chiral (non-racemic) alkoxy acetylene dicobalt hexacarbonyl complexes. The major adduct from (1R, 2S)-2-phenylcyclohexyloxyethyne and norbomadiene, isolated in 58% yield, is shown to be useful for obtaining chiral 4-substituted 2-cyclopentenones.

引用

页码：575 / 578

页数：4

共 27 条

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