SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL-STRUCTURES OF COPPER(II) AND NICKEL(II) THIOCYANATE COMPLEXES WITH ETHANOLAMINE - A NEW STRUCTURE FOR AN AMINOALKOXIDE CLUSTER

被引：31

作者：

HURSTHOUSE, MB

IZOD, KJ

MAZID, MA

THORNTON, P

机构：

[1] Department of Chemistry, Queen Mary and Westfield College, London El 4NS, Mile End Road

来源：

POLYHEDRON | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)86230-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new antiferromagnetic polymer [Cu(NH2C2H4O)(NCS)]∞ has been prepared and shown by X-ray crystallography to contain a new polymeric linkage of pairs of copper(II) atoms linked alternately by two oxygen bridges and one weaker thiocyanate bridge. Electronic, ESR and IR spectra and temperature-variable magnetochemical data are described. [Ni(NH2C2H4OH)2(NCS)2] is fully characterized by its magnetism, electronic and IR spectra and crystal structure as a centrosymmetric octahedral monomer with nitrogen-coordinated thiocyanates. © 1990.

引用

页码：535 / 539

页数：5

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