ISOTOPICALLY SELECTIVE ELECTRON-TRANSFER BETWEEN FREE-RADICAL CATIONS AND THEIR PARENT MOLECULES ENABLES ISOTOPE ENRICHMENT

被引：9

作者：

LIU, ZL

LU, JM

CHEN, P

WANG, XL

WEN, XL

YANG, L

LIU, YC

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000076

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron transfer between the thianthrene radical cation and its neutral molecule precursor shows a significant H/D equilibrium isotope effect which may be used for isotopic enrichment.

引用

页码：76 / 77

页数：2

共 5 条

[1] LAURICELLA TL, 1988, J PHYS CHEM-US, V92, P3678
[2] ION RADICALS .18. REACTIONS OF THIANTHRENIUM PERCHLORATE AND THIANTHRENIUM TRICHLORODIIODIDE
MURATA, Y
SHINE, HJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (11) : 3368 - &
[3] DIMINISHED SOLUTION ELECTRON-AFFINITIES OF C-13-SUBSTITUTED AND DEUTERIUM-SUBSTITUTED ANION RADICAL PRECURSORS ALLOW ISOTOPIC ENRICHMENT
STEVENSON, GR
ESPE, MP
REITER, RC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (03) : 532 - 533
[4] ISOTOPIC ENRICHMENTS VIA ALTERED 1ST AND 2ND SOLUTION ELECTRON-AFFINITIES
STEVENSON, GR
ESPE, MP
REITER, RC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (19) : 5760 - 5762
[5] STEVENSON GR, 1988, J PHYS CHEM-US, V92, P6580

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