REACTION OF 1,2-BORYLPHOSPHINOETHENE WITH THIOCYANATES - MOLECULAR AND CRYSTAL-STRUCTURE OF 2,2,3-TRIBUTYL-4,5,5-TRIPHENYL-6-METHYLTHIO-1,5,2-AZAPHOSPHONIABORATACYCLOHEXA-3,6-DIENE

被引：4

作者：

ARBUZOV, BA

NIKONOV, GN

BALUEVA, AS

KAMALOV, RM

STEPANOV, GS

PUDOVIK, MA

LITVINOV, IA

LENSTRA, ATH

GEISE, HJ

机构：

[1] A.E. Arbuzov Institute of Organic and Physical Chemistry Kazan Scientific Center, Russian Academy of Sciences, Kazan

来源：

BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 07期

关键词：

1,2-BORYLPHOSPHINOETHENE; ALKYLTHIOCYANATE; 6-ALKYLTHIO-1,5,2-AZAPHOSPHONIABORATACYCLOHEXA-3,6-DIENE; STRUCTURE;

D O I：

10.1007/BF00864194

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 1,2-borylphosphinoethenes with alkylthiocyanates leads to formation of substances having the structure of 6-alkylthio-1,5,2-azaphosphoniaboratacyclohexa-3,6-dienes in the crystal state. The structure of the compounds has been proven by x-ray diffraction analysis of 2,2,3-tributyl-4,4,5-triphenyl-5-methylthio-1,5,2-azaphosphoniaboratacyclohexa-3,6-diene. The heterocyclic moiety of the molecule is planar within 0.010(2) angstrom. The methylthio group lies practically in the plane of the heterocycle.

引用

页码：1266 / 1271

页数：6

共 10 条

[1]

ARBUZOV BA, 1991, IAN SSSR KH, P2428

[2]

BALUEVA AS, 1991, IAN SSSR KH, P1209

[3]

BALUEVA AS, 1990, IAN SSSR KH, P2613

[4] CRYSTAL AND MOLECULAR STRUCTURE OF 1,1,2,4,4,5-HEXAPHENYL-L,4-DIPHOSPHONIACYCLOHEXADIENE-2,5 DIBROMIDE [J].

BROWN, JN ;

TREFONAS, LM .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1972, 9 (02) :187-&

[5]

KAMALOV RM, 1990, ZH OBSHCH KHIM+, V60, P476

[6]

KAMALOV RM, 1989, DOKL AKAD NAUK SSSR, V308, P138

[7]

Michalski J., 1959, ROCZN CHEM, V33, P105

[8] CRYSTAL AND MOLECULAR STRUCTURE OF 1,1,4,4-TETRAETHYL-2,5-DIMETHYL-1,4-DIPHOSPHONIACYCLOHEXADIENE-1,4-DIBROMIDE [J].

TOWNS, RLR ;

MAJESTE, R ;

BROWN, JN ;

TREFONAS, LM .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1970, 7 (04) :835-&

[9]

ZIMIN MG, 1986, ZH OBSHCH KHIM+, V56, P2660

[10] REACTIONS OF DIALKYL DITHIOPHOSPHORIC AND DIPHENYLDITHIOPHOSPHINIC ACIDS WITH THIOCYANATES [J].

ZIMIN, MG ;

KAMALOV, RM ;

CHERKASOV, RA ;

PUDOVIK, AN .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1982, 13 (03) :371-378

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