SYNTHESIS AND CRYSTAL-STRUCTURE OF DIOXOBIS(MU-PENTAFLUOROPHENYLIMIDO)DI-(MU-METHYLCYCLOPENTADIENYL)DIMOLYBDENUM

被引：5

作者：

FAWCETT, J

HOLLOWAY, JH

HOPE, EG

RUSSELL, DR

SAUNDERS, GC

ATHERTON, MJ

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

[2] BNFL FLUOROCHEM LTD,PRESTON PR4 0XJ,LANCS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 01期

关键词：

MOLYBDENUM; IMIDE; ORE; PENTAFLUOROPHENYL; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87025-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between Cg F(5)N0(2) and [(eta-MeC(5)H(4),)Mo(CO)(3)](2) yields the dioxobisimido complex, [(eta-MeC(5)H(4))MoO(eta-NC6F5)](2) (1). The X-ray crystal structure of compound 1 shows a cis arrangement of the methylcyclopentadienyl ligands and a puckered metallacyclic core.

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页码：C20 / C22

页数：3

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