PHASE SEPARATED ZONE DIMENSIONS IN WATER SWOLLEN POLYDIMETHYLSILOXANE POLYMETHACRYLIC ACID INTERPENETRATING NETWORKS

被引：13

作者：

MCGAREY, B ^{[1
]}

RICHARDS, RW ^{[1
]}

机构：

[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND

来源：

BRITISH POLYMER JOURNAL | 1987年 / 19卷 / 02期

关键词：

HEAVY WATER - NEUTRONS - Scattering;

D O I：

10.1002/pi.4980190204

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Interpenetrating networks of polydimethylsiloxane and polymethacrylic acid have been prepared. The structure of these materials swollen in heavy water has been investigated using small angle neutron scattering. A correlation function has been used to describe this structure, and it is found that the characteristic correlation length of the swollen polymethacrylic acid phase increases linearly with composition. The presence of a diffuse interface between the two phases is indicated from an analysis of the scattered intensity at high scattering vectors.

引用

页码：111 / 117

页数：7

共 20 条

[1]

[Anonymous], 1970, XRAY DIFFRACTION MET

[2] SCATTERING BY AN INHOMOGENEOUS SOLID [J].

DEBYE, P ;

BUECHE, AM .

JOURNAL OF APPLIED PHYSICS, 1949, 20 (06) :518-525

[3] SCATTERING BY AN INHOMOGENEOUS SOLID .2. THE CORRELATION FUNCTION AND ITS APPLICATION [J].

DEBYE, P ;

ANDERSON, HR ;

BRUMBERGER, H .

JOURNAL OF APPLIED PHYSICS, 1957, 28 (06) :679-683

[4]

GHOSH RE, 81GH29T ILL TECHN RE

[5]

Guinier A., 1955, SMALL ANGLE SCATTERI

[6]

HELFAND E, 1982, DEV BLOCK COPOLYMERS, V1

[7]

MCGAREY B, POLYMER, V27, P1315

[8]

MCGAREY B, UNPUB

[9] DIE RONTGENKLEINWINKELSTREUUNG VON DICHTGEPACKTEN KOLLOIDEN SYSTEMEN .2. [J].

POROD, G .

KOLLOID-ZEITSCHRIFT AND ZEITSCHRIFT FUR POLYMERE, 1952, 125 (02) :108-122

[10] DIE RONTGENKLEINWINKELSTREUUNG VON DICHTGEPAKTEN KOLLOIDEN SYSTEMEN .2. [J].

POROD, G .

KOLLOID-ZEITSCHRIFT AND ZEITSCHRIFT FUR POLYMERE, 1952, 125 (01) :51-57

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