SYNTHESIS OF A NAGILACTONE ANALOG FROM TOTAROL

被引：17

作者：

BENDALL, JG ^{[1
]}

CAMBIE, RC ^{[1
]}

RUTLEDGE, PS ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1992年 / 45卷 / 06期

关键词：

D O I：

10.1071/CH9921005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Totarol (1) has been converted into the nagilactone-A analogue (25) by oxidative decarboxylation of the acid (18). Acid (18) was formed from the benzyl ester (20) after removal of the protecting group by hydrogenolysis, thereby circumventing a difficult hydrolysis step encountered in a previous conversion of the methyl ester (19) into (25).

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页码：1005 / 1019

页数：15

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