SAMARIUM-CATALYZED ELECTROCHEMICAL REDUCTION OF ORGANIC HALIDES

被引：15

作者：

HEBRI, H

DUNACH, E

PERICHON, J

机构：

[1] Laboratoire d’ Electrochimie, Catalyse et Synthese Organique, 94320 Thiais, UMR-28, CNRS, 2, rue H. Dunant

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 22期

关键词：

D O I：

10.1080/00397919108021598

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electroreduction of a series of organic halides including chloro- and fluoroderivatives bearing various functional groups is effected in good yields in the presence of a catalytical amount of SmCl3. Reactions are carried out in DMF in a single-compartment cell fitted with a consumable magnesium anode.

引用

页码：2377 / 2382

页数：6

共 15 条

[1]

BAIZER MM, 1983, ORGANIC ELECTROCHEMI, pCH7

[2]

CASANOVA J, 1973, CHEM CARBON HALOGE 2, pCH15

[3]

CHAUSSARD J, 1990, SYNTHESIS-STUTTGART, V5, P369

[4] A MILD AND CONVENIENT METHOD FOR THE REDUCTION OF ORGANIC HALIDES BY USING A SMI2-THF SOLUTION IN THE PRESENCE OF HEXAMETHYLPHOSPHORIC TRIAMIDE (HMPA) [J].