DIELECTRIC POLARIZATION AND POLARIZABILITY OF 1-PENTANOL + N-OCTANE MIXTURES FROM STATIC DIELECTRIC-CONSTANT AND REFRACTIVE-INDEX DATA AT 0,25 AND 45-DEGREES-C

被引：13

作者：

DAPRANO, A

DONATO, ID

机构：

[1] Department of Physical Chemistry, University of Palermo, Palermo, 90123

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1990年 / 19卷 / 09期

关键词：

1-pentanol+n-octane; Dielectric constant; dipole-dipole interactions; hydrogen bond; refractive index; temperature dependence;

D O I：

10.1007/BF00653073

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Static dielectric constants and refractive indices of 1-pentanol+n-octane mixtures were measured in the temperature range between 0 and 45°C. Data discussed in terms of Kirkwood correlation factor and Lorentz-Lorenz molar refractivity give information on the short range intermolecular interactions between the components. The role played by the nonpolar n-octane in the destruction of 1-pentanol oligomers is also pointed out. © 1990 Plenum Publishing Corporation.

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页码：883 / 892

页数：10

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