STRUCTURE OF ADSORPTION LAYERS OF IONIC SURFACTANTS AT THE SOLID LIQUID INTERFACE

被引：145

作者：

RUPPRECHT, H

GU, T

机构：

[1] Institut für Pharmazie, Universität Regensburg, Regensburg, D-8400

来源：

COLLOID AND POLYMER SCIENCE | 1991年 / 269卷 / 05期

关键词：

ADSORPTION LAYER; SURFACTANT ADSORPTION; SURFACE AGGREGATE; HEMIMICELLE; ADSORPTION MODEL; COIONS EFFECTS; COUNTERIONS EFFECTS; HEAD GROUPS EFFECTS; ELECTROLYTE EFFECTS; PH EFFECTS; SURFACE POLARITY; POROSITY; SURFACE CHARGE DENSITY; ELECTROSTATIC INTERACTION; HYDROPHOBIC INTERACTION;

D O I：

10.1007/BF00655889

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A large number of experimental results of different surfactant adsorption systems (mainly on the silicas) obtained from both equilibrium and kinetic studies under different conditions are interpreted by a model of small individual surface aggregates. The adsorption model is contrasted with the influences of various factors, including electrostatic interaction, hydrophobic interaction, concentrations, types of coions, types of counterions, surfactant structure, alkyl chain length, types of head groups, neutral electrolytes, pH, adsorbent structure, porosity, surface charge density, and surface polarity.

引用

页码：506 / 522

页数：17

共 82 条

[1] THE ORIENTATIONAL BINDING OF SUBSTITUTED BENZOATE ANIONS AT THE CETYLTRIMETHYL AMMONIUM BROMIDE INTERFACE [J].