HIGH-PRESSURE STOPPED-FLOW STUDY OF THE COMPLEXATION OF VANADIUM(II) WITH THIOCYANATE IN WATER - FURTHER EVIDENCE FOR THE ASSOCIATIVE CHARACTER OF SUBSTITUTION ON THIS METAL-ION

被引：44

作者：

NICHOLS, PJ ^{[1
]}

DUCOMMUN, Y ^{[1
]}

MERBACH, AE ^{[1
]}

机构：

[1] UNIV LAUSANNE,INST CHIM MINERALE & ANALYT,CH-1005 LAUSANNE,SWITZERLAND

来源：

INORGANIC CHEMISTRY | 1983年 / 22卷 / 26期

关键词：

D O I：

10.1021/ic00168a035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：3993 / 3995

页数：3

共 25 条

[1]

Baker B., UNPUB

[2] KINETICS OF OXIDATION OF VANADIUM(2) BY IRON(3) AND CHROMIUM(3) COMPLEXES [J].

BAKER, BR ;

ORHANOVI.M ;

SUTIN, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (03) :722-+

[3]

BURGESS J, 1978, METAL IONS SOLUTION, pCH11

[4] ACTIVATION VOLUMES FOR THE LIGAND-SUBSTITUTION REACTIONS OF NICKEL(II) AND COBALT(II) CATIONS WITH PYRIDINE-2-AZO-4-DIMETHYLANILINE IN VARIOUS SOLVENTS [J].

CALDIN, EF ;

GREENWOOD, RC .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, 77 :773-782

[5] KINETICS AND THERMODYNAMICS OF COMPLEX-FORMATION OF NICKEL(II) AND COBALT(II) IONS WITH AMMONIA AND PYRIDINE-2-AZODIMETHYLANILINE IN WATER, AT PRESSURES FROM 1 BAR TO 2 KBAR [J].

CALDIN, EF ;

GRANT, MW ;

HASINOFF, BB .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1972, 68 (12) :2247-&

[6] HIGH-PRESSURE TEMPERATURE-JUMP EVIDENCE FOR AN IA MECHANISM FOR SUBSTITUTION-REACTIONS OF MANGANESE(II) IN AQUEOUS-SOLUTION [J].

DOSS, R ;

VANELDIK, R .

INORGANIC CHEMISTRY, 1982, 21 (11) :4108-4109

[7] HIGH-PRESSURE NMR KENETICS .9. HIGH-PRESSURE O-17-FT-NMR - EVIDENCE FOR THE ASSOCIATIVE NATURE OF SUBSTITUTION-REACTIONS ON MN2+ IN WATER [J].

DUCOMMUN, Y ;

NEWMAN, KE ;

MERBACH, AE .

HELVETICA CHIMICA ACTA, 1979, 62 (07) :2511-2516

[8] HIGH-PRESSURE NMR KINETICS .11. HIGH-PRESSURE O-17 NMR EVIDENCE FOR A GRADUAL MECHANISTIC CHANGEOVER FROM IA TO ID FOR WATER EXCHANGE ON DIVALENT OCTAHEDRAL METAL-IONS GOING FROM MANGANESE(II) TO NICKEL(II) [J].

DUCOMMUN, Y ;

NEWMAN, KE ;

MERBACH, AE .

INORGANIC CHEMISTRY, 1980, 19 (12) :3696-3703

[9] HIGH-PRESSURE NMR - KINETICS .15. HIGH-PRESSURE O-17-LABELED NMR - STUDY OF VANADIUM(II) IN WATER A 2ND EXAMPLE OF AN ASSOCIATIVE INTERCHANGE MECHANISM (IA) FOR SOLVENT EXCHANGE ON AN OCTAHEDRAL DIVALENT TRANSITION-METAL ION [J].

DUCOMMUN, Y ;

ZBINDEN, D ;

MERBACH, AE .

HELVETICA CHIMICA ACTA, 1982, 65 (05) :1385-1390

[10]

ERDEY L, 1953, ACTA CHIM HUNG, V3, P469

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