OXYGEN-TRANSFER CATALYSIS BY CHEMICAL ANALOGS OF MONOOXYGENASES

被引：7

作者：

SHTEINMAN, AA

机构：

[1] Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Chernogolovka, 142432, Moscow Region

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 02期

关键词：

ALKANES; OXIDATION; METAL COMPLEXES; ALKANE ACTIVATION; DIOXYGEN ACTIVATION; MONOOXYGENASES; BIOMIMETICS;

D O I：

10.1007/BF00697065

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New chemical analogs of monooxygenases and new reactions of alkane oxidation mediated by complexes are reviewed. Mechanisms of dioxygen and alkane activation and those of oxygen transfer from O-2 and active oxygen donors to C-H bonds via ferryl and other intermediates are discussed.

引用

页码：227 / 234

页数：8

共 30 条

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