SYNTHESIS OF 5,6,17,18-BISDEHYDROTETRATHIA[24]ANNULENE[2.2.2.2] - A STRAINED PLANAR ANNULENE DEVOID OF PERIPHERAL CONJUGATION

被引：31

作者：

KAWASE, T ^{[1
]}

DARABI, HR ^{[1
]}

UCHIMIYA, R ^{[1
]}

ODA, M ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 07期

关键词：

D O I：

10.1246/cl.1995.499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5,6,17,18-Bisdehydrotetrathia[24]annulene [2.2.2.2], synthesized through a sequence of the McMurry coupling of 1,1-dichloro-2,2-di(5-formyl-2-thienyl)ethene and a novel double Fritsch-Buttenberg-Wiechell rearrangement, has a planar X-ray structure with bent triple bonds and short S-S contacts but shows little sign of peripheral conjugation.

引用

页码：499 / 500

页数：2

共 10 条

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