NONSTATIONARY POLYMERIZATION OF STYRENE BY HCLO4 IN CH2CL2

被引：42

作者：

LORIMER, JP ^{[1
]}

PEPPER, DC ^{[1
]}

机构：

[1] UNIV DUBLIN, TRINITY COLL, CHEM LAB, DUBLIN, IRELAND

来源：

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES | 1976年 / 351卷 / 1667期

关键词：

D O I：

10.1098/rspa.1976.0156

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The paper describes a detailed study on the polymerization reaction of the initial phase in the temperature range of minus 60 to minus 80 degree C. It also demonstrates that the intermediate is ionic (by observation of synchronous conductivity) but also shows that even in this initial stage there is a parallel non-ionic component in the conversion.

引用

页码：551 / 568

页数：18

共 24 条

[1] KINETICS OF ACID-CATALYSED CYCLISATION OF DISTYRENE + DI-( ALPHA-METHYLSTYRENE )
BARTON, JM
PEPPER, DC
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (MAY): : 1573 - &
[2] STOPPED-FLOW APPARATUS WITH TEMPERATURE CONTROL, FIBER OPTICS, AND CHEMICALLY INERT FLOW SYSTEM
CALDIN, EF
CROOKS, JE
QUEEN, A
[J]. JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1973, 6 (09): : 930 - 932
[3] CHMELIR M, 1975, MAKROMOL CHEM, V176, P2099
[4] CHMELIR M, 1973, 7 ROUEN S CAT POLYM, P1
[5] HOMOCONJUGATIONAL IONIZATION REACTION OF ANHYDROUS PERCHLORIC ACID IN DICHLOROMETHANE
COUTAGNE, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (06) : 1518 - &
[6] MOLECULAR WEIGHTS IN CATIONIC POLYMERISATION OF STYRENE BY PERCHLORIC ACID
DARCY, LE
MILLRINE, WP
PEPPER, DC
[J]. CHEMICAL COMMUNICATIONS, 1968, (22) : 1441 - &
[7] DARCY LE, 1967, THESIS DUBLIN U
[8] DARCY LE, 1966, IUPAC S MACROMOLECUL, P42
[9] KINETICS AND MECHANISM OF COBALT(III) OXIDATION OF MANGANESE(II) AND IRON(II) IN ACID PERCHLORATE SOLUTION
DAVIES, G
[J]. INORGANIC CHEMISTRY, 1971, 10 (06) : 1155 - &
[10] DESORGO M, 1973, CHEM COMMUN, P419

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