MALONYLATED FLAVONE 5-O-GLUCOSIDES IN THE BARREN SPROUTS OF EQUISETUM-ARVENSE

被引:67
作者
VEIT, M
GEIGER, H
CZYGAN, FC
MARKHAM, KR
机构
[1] UNIV HOHENHEIM,INST CHEM,W-7000 STUTTGART 70,GERMANY
[2] DSIR,DIV CHEM,PETONE,NEW ZEALAND
关键词
!sup]13[!/sup]C NMR; chemotaxonomy; Equisetaceae; Equisetum arvense; flavone 5-O-(6″-O-malonyl-β-d-glucopyranosides); flavonoids; horsetail;
D O I
10.1016/0031-9422(90)85187-K
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Equisetum arvense exists as two chemotypes one occurring in Asia and North America and the other in Europe. Barren sprouts from Asia and North America contain flavone 5-glucosides and their malonyl esters, whereas European material is free from these compounds. Both types contain quercetin 3-O-β-d-glucopyranoside, and its malonyl ester. Quercetin 3-O-sophoroside, genkwanin 4′-O-β-d-glucopyranoside and protogenkwanin 4′-O-β-d-glucopyranoside are only found in European material. The structures of all new compounds are proven. © 1990.
引用
收藏
页码:2555 / 2560
页数:6
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