SOLVENT MODULATION OF THE 1ST HYPERPOLARIZABILITY OF DMABN - AN APPROXIMATE THEORETICAL-ANALYSIS

被引：11

作者：

SEN, R

MAJUMDAR, D

BHATTACHARYYA, SP

机构：

[1] Department of Physical Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 190卷 / 05期

关键词：

D O I：

10.1016/0009-2614(92)85170-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An approximate molecular orbital theoretical calculation of the solvent modulation of the frequency-dependent first hyperpolarizability beta(omega) of p-dimethylaminobenzonitrile (DMABN) shows a significant solvent polarity effect, especially in the low dielectric constant (epsilon) region. The zero-frequency beta turns out to be a quadratic function of the solvent polarity function f(epsilon).

引用

页码：443 / 446

页数：4

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