TOWARD A MOLECULAR-SIZE TINKERTOY CONSTRUCTION SET - PREPARATION OF TERMINALLY FUNCTIONALIZED [N]STAFFANES FROM [1.1.1]PROPELLANE

被引：192

作者：

KASZYNSKI, P ^{[1
]}

FRIEDLI, AC ^{[1
]}

MICHL, J ^{[1
]}

机构：

[1] UNIV TEXAS,CTR STRUCT & REACT,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 02期

关键词：

D O I：

10.1021/ja00028a029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile but low-yield synthesis of [n] staffanes (the oligomers of [1.1.1] propellane 1, n = 1-5) functionalized on one or both ends is described, and their properties are summarized. The substituents are -COOCH3, -n-C4H9, -C6H5, -Br, -I, and -SCOCH3, and their conversion to others, such as -COOH, -COCH3 and -SH, is demonstrated. It is proposed that these rod-shaped molecules will be useful in the development of a molecular-size civil engineering construction set analogous to children's toy construction sets.

引用

页码：601 / 620

页数：20

共 112 条

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