HIGH-PRESSURE VISCOELASTIC PROPERTIES AND EQUATION OF STATE OF LIQUIDS DERIVED FROM BRILLOUIN DATA

被引:32
作者
OLIVER, WF [1 ]
HERBST, CA [1 ]
LINDSAY, SM [1 ]
WOLF, GH [1 ]
机构
[1] ARIZONA STATE UNIV,DEPT CHEM,TEMPE,AZ 85287
关键词
D O I
10.1103/PhysRevLett.67.2795
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Brillouin scattering in an organic glass-forming liquid up to a pressure of 12 GPa is reported. The onset of the unrelaxed regime is indicated by a distinct maximum in the acoustic attenuation at a pressure P-alpha, above which weak shear modes are resolved. Sound velocity data are fitted in a self-consistent way which accounts for relaxation by combining the "universal" Vinet equation of state with an expression for the dynamical modulus. This analysis yields the pressure dependences of the relaxed and unrelaxed moduli, relaxation time, and density over the pressure range studied.
引用
收藏
页码:2795 / 2798
页数:4
相关论文
共 29 条
[1]   PRESSURE DEPENDENCE OF ULTRASONIC ABSORPTION IN TOLUENE AND HEXANE [J].
ALLEGRA, J ;
HAWLEY, S ;
HOLTON, G .
JOURNAL OF THE ACOUSTICAL SOCIETY OF AMERICA, 1970, 47 (1P2) :144-&
[2]   Transport in Ionic Liquids Under Pressure. II. Concentrated Calcium Nitrate-Water and Magnesium Chloride-Water Solutions [J].
Angell, C. A. ;
Pollard, L. J. ;
Strauss, W. .
JOURNAL OF SOLUTION CHEMISTRY, 1972, 1 (06) :517-530
[3]   SHORT-TIME STRUCTURAL RELAXATION PROCESSES IN LIQUIDS - COMPARISON OF EXPERIMENTAL AND COMPUTER-SIMULATION GLASS TRANSITIONS ON PICOSECOND TIME SCALES [J].
ANGELL, CA ;
TORELL, LM .
JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (02) :937-945
[4]   Freezing parameters and compressions of twenty-one substances to 50,000 kg/cm(2) [J].
Bridgman, PW .
PROCEEDINGS OF THE AMERICAN ACADEMY OF ARTS AND SCIENCES, 1942, 74 (12/14) :399-424
[5]   VELOCITY OF SOUND AND EQUATIONS OF STATE FOR METHANOL AND ETHANOL IN A DIAMOND-ANVIL CELL [J].
BROWN, JM ;
SLUTSKY, LJ ;
NELSON, KA ;
CHENG, LT .
SCIENCE, 1988, 241 (4861) :65-67
[6]   RAYLEIGH-BRILLOUIN SPECTROSCOPY OF SIMPLE VISCOELASTIC LIQUIDS [J].
CARROLL, PJ ;
PATTERSON, GD .
JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (04) :1666-1675
[7]  
CHANGSHENG Z, 1984, MAT RES SOC S P, V22, P61
[8]   ULTRASONIC AND HYPERSONIC PROPERTIES OF MOLTEN KNO3-CA(NO3)2 MIXTURE [J].
CHENG, LT ;
YAN, YX ;
NELSON, KA .
JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (10) :6052-6061
[9]   ULTRASONIC-ABSORPTION AND SOUND-SPEED DATA FOR 9 LIQUIDS AT HIGH PRESSURES [J].
HAWLEY, S ;
ALLEGRA, J ;
HOLTON, G .
JOURNAL OF THE ACOUSTICAL SOCIETY OF AMERICA, 1970, 47 (1P2) :137-&
[10]  
HERBST CA, IN PRESS