DIALDEHYDE PLUS DIAMINE - POLYMER OR MACROCYCLE

被引：67

作者：

BRUNNER, H

SCHIESSLING, H

机构：

[1] Institut Für Anorganische Chemie, Universität Regensburg

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 01期

关键词：

D O I：

10.1002/anie.199401251

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 24‐membered macrocycle 1 is surprisingly generated from (S)‐2,2′‐dihydroxy‐1,1′‐binaphthyl‐3,3′‐dialdehyde [(S)‐(2)] and (R,R)‐1,2‐diamino‐1,2‐diphenylethane, whereas in the same reaction (R)‐2 yields the polymeric Schiff base as expected. Macrocycle 1 can be used for an economical and simple enantiomeric resolution of 2. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：125 / 126

页数：2

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