STUDIES ON THE BORON-NITROGEN BOND-LENGTH OF THE CLASSICAL DONOR-ACCEPTOR COMPLEX H3N-BF3

被引：50

作者：

JONAS, V ^{[1
]}

FRENKING, G ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001489

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quantum mechanical calculations at correlated levels using different basis sets predict that the B-N bond length of H3N-BF3 is 1.68 +/- 0.02 Angstrom; the previously reported value of 1.59 +/- 0.03 Angstrom, which is based on microwave spectroscopic investigations, is probably too short.

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页码：1489 / 1490

页数：2

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