X-RAY STRUCTURE-ANALYSIS AND REACTIVITY OF THE ZIRCONAAZAPHOSPHIRANE CP2ZR(CL)N(SIME3)P(H)N(SIME3)2

被引：36

作者：

DUFOUR, N

MAJORAL, JP

CAMINADE, AM

CHOUKROUN, R

DROMZEE, Y

机构：

[1] UNIV PAUL SABATIER,CHIM COORDINAT LAB,CNRS,UPR 8241,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

[2] UNIV PARIS 06,CHIM MET TRANSIT LAB,F-75230 PARIS 05,FRANCE

[3] INST POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1021/om00047a024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of the 18-electron complex Cp2-Activated-Zr(Cl)N(SiMe3)P(H)N(SiMe3)2 (3a) has been determined by single-crystal X-ray diffraction. Reaction of 3a with MeOSO2CF3 and Me3SiOSO2CF3 leads, with ring retention, to the neutral and cationic zirconium phosphorus species 9 and 10, respectively, while ring opening with formation of a phosphorus-iron complex or phosphorus sulfide or selenide occurs when 3a is treated with Fe2(CO)9, S8, or Se, respectively.

引用

页码：45 / 48

页数：4

共 17 条

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