SYNTHESIS, X-RAY CRYSTAL-STRUCTURE, EQUILIBRATION STUDIES AND ANION CHEMISTRY OF TRANS-1,3-DITHIANE 1,3-DIOXIDE

被引：14

作者：

AGGARWAL, VK ^{[1
]}

DAVIES, IW ^{[1
]}

FRANKLIN, RJ ^{[1
]}

MADDOCK, J ^{[1
]}

MAHON, MF ^{[1
]}

MOLLOY, KC ^{[1
]}

机构：

[1] UNIV BATH,XRAY CRYSTALLOG UNIT,BATH BA2 7AY,AVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 03期

关键词：

D O I：

10.1039/p19910000662

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

trans-1,3-Dithiane 1,3-dioxide, prepared by stereoselective oxidation of 1,3-dithiane has been found to be thermodynamically more stable than the cis-isomer by equilibration studies using N2O4 and has been found to undergo highly selective (20:1) aldol type reactions with benzaldehyde.

引用

页码：662 / 664

页数：3

共 26 条

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