APPLICATION OF THE LIGAND POLYHEDRAL MODEL TO DICOBALT OCTACARBONYL

被引：7

作者：

JOHNSON, BFG

PARISINI, E

机构：

[1] Department of Chemistry, University of Edinburgh, Edinburgh, EH9 3JJ Scotland, West Mains Road

来源：

INORGANICA CHIMICA ACTA | 1992年 / 198卷

关键词：

D O I：

10.1016/S0020-1693(00)92376-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Application of the ligand polyhedral model (LPM) to dicobalt octacarbonyl, [Co2(CO)8], leads to an explanation of the mu-2-bridged structure that the molecule adopts in the solid state and also of the isomeric forms which coexist in equilibrium in solution. It further provides a convenient explanation of both the observed low energy interconversion of these isomers and the fluxional behaviour they exhibit.

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页码：345 / 349

页数：5

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