PARTIAL HYDROLYSIS OF A SCHIFF-BASE TRIPODAL LIGAND-INDUCED BY COPPER(II) SALTS - CRYSTAL-STRUCTURE OF THE PRODUCT FROM REACTION WITH COPPER(II) PERCHLORATE

被引：14

作者：

FENTON, DE ^{[1
]}

WESTWOOD, GP ^{[1
]}

BASHALL, A ^{[1
]}

MCPARTLIN, M ^{[1
]}

SCOWEN, IJ ^{[1
]}

机构：

[1] UNIV N LONDON,SCH APPL CHEM,LONDON N7 8DB,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 14期

关键词：

D O I：

10.1039/dt9940002213

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cu(ClO4)2 or Cu(NO3)2 with a potentially heptadentate Schiff-base tripod derived from tris(2-aminoethyl)amine and 2-hydroxyacetophenone occurs with accompanying hydrolysis of the ligand; single-crystal X-ray structure analysis of the product involving Cu (ClO4)2 shows the ligand to exist in a zwitterionic form and provide a near square-planar environment for the copper(II) cation.

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页码：2213 / 2214

页数：2

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