PALLADIUM CROSS-COUPLING REACTIONS OF ARYL FLUOROSULFONATES - AN ALTERNATIVE TO TRIFLATE CHEMISTRY

被引：94

作者：

ROTH, GP ^{[1
]}

FULLER, CE ^{[1
]}

机构：

[1] BRISTOL MYERS SQUIBB PHARMACEUT,RES INST,CHEM PROC RES,SYRACUSE,NY 13221

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 11期

关键词：

D O I：

10.1021/jo00011a010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and efficient electrophilic partner for palladium(O)-catalyzed cross coupling is reported. Aryl fluorosulfonates are readily prepared in high yield by treatment of the appropriate phenol with fluorosulfonate anhydride. The palladium-catalyzed coupling reactions of these fluorosulfonates with vinyl- and aryltin reagents, as well as organozinc chlorides, takes place under mild conditions in a regio- and stereoselective manner.

引用

页码：3493 / 3496

页数：4

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