ALKANE OXIDATION BY POLYNUCLEAR NONHEME IRON COMPLEXES - AN IMIDAZOLE EFFECT

被引：20

作者：

FONTECAVE, M

ROY, B

LAMBEAUX, C

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 14期

关键词：

D O I：

10.1039/c39910000939

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Binuclear and trinuclear non-heam iron complexes efficiently transfer oxidizing equivalents from tert-butyl hydroperoxide to cyclohexane; imidazole in excess greatly increases the yield of the reaction and the ketone : alcohol ratio.

引用

页码：939 / 940

页数：2

共 12 条

[1] CONVENIENT, HIGH-YIELD SYNTHESIS OF (ET4N)2[FE2OCL6]
ARMSTRONG, WH
LIPPARD, SJ
[J]. INORGANIC CHEMISTRY, 1985, 24 (06) : 981 - 982
[2] MECHANISM OF THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS BY GIF SYSTEMS - RELATIONSHIP WITH METHANE MONOOXYGENASE
BARTON, DHR
CSUHAI, E
DOLLER, D
OZBALIK, N
BALAVOINE, G
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1990, 87 (09) : 3401 - 3404
[3] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .4. THE GIF SYSTEM FOR SELECTIVE OXIDATION USING MOLECULAR-OXYGEN
BARTON, DHR
BOIVIN, J
GASTIGER, M
MORZYCKI, J
HAYMOTHERWELL, RS
MOTHERWELL, WB
OZBALIK, N
SCHWARTZENTRUBER, KM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (06): : 947 - 955
[4] HYDROXYLATION OF ALKANES BY HYDROGEN-PEROXIDE - AN EFFICIENT SYSTEM USING MANGANESE PORPHYRINS AND IMIDAZOLE AS CATALYSTS
BATTIONI, P
RENAUD, JP
BARTOLI, JF
MANSUY, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (04) : 341 - 343
[5] PREPARATION AND PROPERTIES OF IRON(III)-AMINO ACID COMPLEXES - IRON(III)-ALANINE, A POSSIBLE FERRITIN ANALOG
HOLT, EM
HOLT, SL
TUCKER, WF
ASPLUND, RO
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (08) : 2621 - 2623
[6] HYDROXYLATION OF ALKANES AND ARENES USING MOLECULAR-OXYGEN
KITAJIMA, N
ITO, M
FUKUI, H
MOROOKA, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (02) : 102 - 104
[7] ALKANE FUNCTIONALIZATION BY NON-PORPHYRIN IRON COMPLEXES - MECHANISTIC INSIGHTS
LEISING, RA
NORMAN, RE
QUE, L
[J]. INORGANIC CHEMISTRY, 1990, 29 (14) : 2553 - 2555
[8] OXO-BRIDGED POLYIRON CENTERS IN BIOLOGY AND CHEMISTRY
LIPPARD, SJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (03): : 344 - 361
[9] METALLOPORPHYRIN-CATALYZED HYDROXYLATION OF CYCLOHEXANE BY ALKYL HYDROPEROXIDES - PRONOUNCED EFFICIENCY OF IRON-PORPHYRINS
MANSUY, D
BARTOLI, JF
CHOTTARD, JC
LANGE, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1980, 19 (11): : 909 - 910
[10] CRYSTAL AND MOLECULAR-STRUCTURE OF THE (MU-OXO)BIS[AQUOBIS(PHENANTHROLINE)IRON(III)] COMPLEX, A RAMAN-SPECTROSCOPIC MODEL FOR THE BINUCLEAR IRON SITE IN HEMERYTHRIN AND RIBONUCLEOTIDE REDUCTASE
PLOWMAN, JE
LOEHR, TM
SCHAUER, CK
ANDERSON, OP
[J]. INORGANIC CHEMISTRY, 1984, 23 (22) : 3553 - 3559

← 1 2 →