STRUCTURAL MACROMOLECULAR PARAMETERS DETERMINING ELECTROCONDUCTIVITY OF OXIDIZED POLY-N-VINYLPYRROLE

被引：5

作者：

CIARDELLI, F

MORI, S

RUGGERI, G

COLLIGIANI, A

CAGNOLATI, R

CAMPANI, E

ROLLA, PA

LUCCHESI, M

机构：

[1] NAPLES UNIV,IST IND AGRARIE,I-80138 NAPLES,ITALY

[2] UNIV PISA,DIPARTIMENTO FIS,I-56100 PISA,ITALY

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1992年 / 59卷

关键词：

D O I：

10.1002/masy.19920590130

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The dependence of electroconductivity on conjugation length as well as the related basic mechanism was investigated by chemical (FeCl3) oxidation of insulating polymers from N-vinylpyrrole (NVP) starting with different Fe/NVP ratios and different molecular weights. The results allow to establish that oxidation occurs mainly intrachain and that electroconductivity has a sharp increase for a conjugation length higher than approximately 15 NVP-units.

引用

页码：363 / 368

页数：6

共 7 条

[1]

ARNES SP, 1987, SYNTHETIC MET, V20, P365

[2] DC ELECTRICAL TRANSPORT IN A NEW CONDUCTING POLYMER - OXIDIZED POLY(N-VINYLPYRROLE) [J].