ALPHA-AMINO-ACIDS CHLORINATION IN AQUEOUS-MEDIA

被引：75

作者：

ARMESTO, XL ^{[1
]}

CANLE, M ^{[1
]}

SANTABALLA, JA ^{[1
]}

机构：

[1] UNIV LA CORUNA,FAC CIENCIAS,DEPT QUIM FUNDAMENTAL & IND,A ZAPATEIRA S-N,E-15071 LA CORUNA,SPAIN

来源：

TETRAHEDRON | 1993年 / 49卷 / 01期

关键词：

D O I：

10.1016/S0040-4020(01)80525-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of chlorination of alpha-amino acids for 6 < pH < 11 has been studied. The reaction is an aliphatic electrophilic substitution, the rate determining step being the transfer of the chlorine atom between the HOCl oxygen and the nitrogen of the alpha-amino acid free amino group.

引用

页码：275 / 284

页数：10

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