ACTIVATED BASIC ALUMINA PROMOTES A MILD, CLEAN AND HIGH-YIELD RACEMIZATION-FREE SYNTHESIS OF T-BUTYL ESTERS FROM CHIRAL ACID BROMIDES AND T-BUTYL ALCOHOL

被引：24

作者：

NAGASAWA, K

OHHASHI, K

YAMASHITA, A

ITO, K

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 02期

关键词：

D O I：

10.1246/cl.1994.209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Esterification of a variety of acid bromides having even steric bulkiness with t-BuOH/activated basic alumina gave the corresponding t-butyl esters in good to excellent yields. In the case of chiral acid bromides, no racemization has been ascertained for the first time.

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页码：209 / 212

页数：4

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