SYNTHESIS OF THE BIS-SPIROACETAL MOIETY OF 17-EPI-20-DEOXYSALINOMYCIN

被引：24

作者：

BRIMBLE, MA

WILLIAMS, GM

机构：

[1] Department of Chemistry and Biochemistry, Massey University, Palmerston North

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 22期

关键词：

D O I：

10.1021/jo00048a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of the bis-spiroacetal moiety of 17-epi-20-deoxysalinomycin (4) is reported in which the key step involves oxidative cyclization of the hydroxy spiroacetals 14 and 15 to the bis-spiroacetals 16 and 17 using (diacetoxyiodo)benzene and iodine under photolytic conditions.

引用

页码：5818 / 5822

页数：5

共 17 条

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