COMPETITIVE UNIMOLECULAR DECOMPOSITION IN CHEMICALLY ACTIVATED RADICAL SYSTEMS - PROPYL RUPTURE

被引：22

作者：

LARSON, CW

TARDY, DC

RABINOVITCH, BS

机构：

[1] Department of Chemistry, University of Washington, Seattle, WA

[2] Department of Chemistry, University of Toronto, Toronto, Ont.

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 49卷 / 01期

关键词：

D O I：

10.1063/1.1669824

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The study of the competitive unimolecular decomposition of chemically activated alkyl radicals is extended to cases of rupture of a propyl fragment vs a methyl or ethyl fragment. A study of the decomposition at room temperature of the octyl-4, heptyl-3, and 3-methyl-hexyl-2 radicals, formed by addition of H atoms to trans-octene-4, trans-heptene-3, and 3-methylhexene-1, is reported. The value of D0° (n-Pr-H) is deduced to be within -0.8 kcal of the value of D0° (Et-H). Comparison of the results are made with values obtained on a theoretical model for the absolute and relative rates; good agreement was found.

引用

页码：299 / +

页数：1

共 14 条

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[6] ELEMENTARY RATES OF DECOMPOSITION OF HOMOLOGOUS SERIES ETHYL THROUGH 2-OCTYL RADICALS
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[J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (05) : 1624 - +
[7] Rabinovitch B.S., 1964, ADV PHOTOCHEM, V3, P1
[8] UNIMOLECULAR DECOMPOSITION OF CHEMICALLY ACTIVATED SEC-BUTYL RADICALS FROM H-ATOMS PLUS CIS-BUTENE-2
RABINOVITCH, BS
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[J]. JOURNAL OF CHEMICAL PHYSICS, 1959, 30 (03) : 735 - 747
[9] Rossini FD., 1953, API PROJECT, V44, P371
[10] SNYDER RG, 1965, SPECTROCHIM ACTA, V21, P169

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