SURFACE-MEDIATED SYNTHESIS OF H4RU4(CO)12, H4OS4(CO)12 ON HYDROXYLATED SILICA

被引：28

作者：

DOSSI, C ^{[1
]}

PSARO, R ^{[1
]}

ROBERTO, D ^{[1
]}

UGO, R ^{[1
]}

ZANDERIGHI, G ^{[1
]}

机构：

[1] CTR CNR,VIA VENEZIA 21,I-20133 MILAN,ITALY

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 22期

关键词：

D O I：

10.1021/ic00347a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The surface reactivity with hydrogen of silica-supported M3(CO)12(M = Ru, Os) has been investigated at atmospheric pressure and temperatures between 25 and 100 °C. Pure H4M4(CO)12complexes are selectively obtained and almost quantitatively recovered from the solid sample by solvent extraction. In the case of H4Os4(CO)12, significative advantages over the conventional synthesis in solution are obtained. © 1990, American Chemical Society. All rights reserved.

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页码：4368 / 4373

页数：6

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