QUANTITATIVE-ANALYSES OF THE 4 ISOMERS OF 3,4-DIPHENYLCYCLOPENTENE BY CHIRAL GAS-CHROMATOGRAPHY

被引：16

作者：

ASUNCION, LA ^{[1
]}

BALDWIN, JE ^{[1
]}

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 18期

关键词：

D O I：

10.1021/jo00123a010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The four isomers of 3,4-diphenylcyclopentene are well resolved by chiral gas chromatography on a Cyclodex B column, eluting in the ordered sequence (3S,4R), (3R,4S), (3S,4S), and(3R,4R). Absolute stereochemical assignments were made through chemical correlations relating the 3,4-diphenylcyclopentenes with a known reference compound, (1S,2S)-(+)-cis-2-phenylcyclopentanol.

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页码：5778 / 5784

页数：7

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