ENANTIOSELECTIVE HYDROGENATION OF ISOPHORONE

被引:46
作者
TUNGLER, A [1 ]
MATHE, T [1 ]
PETRO, J [1 ]
TARNAI, T [1 ]
机构
[1] TECH UNIV BUDAPEST,DEPT ORGAN CHEM TECHNOL,H-1521 BUDAPEST,HUNGARY
来源
JOURNAL OF MOLECULAR CATALYSIS | 1990年 / 61卷 / 03期
关键词
D O I
10.1016/0304-5102(90)80001-Y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of catalyst, pH, hydrogen pressure and intensity of agitation in the enantioselective hydrogenation of isophorone were discussed. The changes in chemical and optical yield of the saturated ketone as functions of conversion and of the water content of the solvent have also been investigated. An iminium salt hydrogenation intermediate has been identified. © 1990.
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页码:259 / 267
页数:9
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