FERROELECTRIC LIQUID-CRYSTALLINE POLYSILOXANES WITH HIGH SPONTANEOUS POLARIZATION AND POSSIBLE APPLICATIONS IN NONLINEAR OPTICS

被引：66

作者：

KAPITZA, H

ZENTEL, R

TWIEG, RJ

NGUYEN, C

VALLERIEN, SU

KREMER, F

WILLSON, CG

机构：

[1] Institut Für Organische Chemie, Universität Mainz, Mainz, D-6500

[2] Institut für Organische Chemie, Makromolekulare Chemie Universität Düsseldorf, Dusseldorf, D-4000

[3] Ibm-Almaden Research Center, San Jose, California, 95120-6099

[4] Max-Planck-Institut für Polymerforschung, Mainz, D-6500

来源：

ADVANCED MATERIALS | 1990年 / 2卷 / 11期

关键词：

D O I：

10.1002/adma.19900021106

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ferroelectric liquid crystalline (LC) polymers (see figure), which in the smectic C* phase exhibit the highest yet known spontaneous polarization for LC polymers of up to 430 nC/cm2, a value which approaches that of the best low molecular weight materials, have been synthesized, based on chiral polysiloxanes. A copolymer is also reported which shows promise for second harmonic generation (frequency doubling) of the 1064 nm Nd:YAG fundamental (to 532 nm) without poling in an external field. (Figure Presented.) Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：539 / 543

页数：5

共 26 条

[1]

Bahr C., Heppke G., Mol. Cryst. Liq. Cryst. Lett, 4, (1986)

[2]

Yoshino K., Ozaki M., Kishio S., Sakurai T., Mikami N., Honma M., New Ferroelectric Liquid Crystals with Spontaneous Polarization Exceeding 10−7C/cm2and Their Electrical and Optical Properties, Molecular Crystals and Liquid Crystals, 144, (1987)

[3]

Mohr K., Kohler S., Worm K., Pelzl G., Diele S., Zaschke H., Demus D., Andersson G., Dahl I., Lagerwall S.T., Skarp K., Stebler B., A Family of Ferroelectric Liquid Crystals with Very High Spontaneous Polarization, Molecular Crystals and Liquid Crystals, 146, (1987)

[4]

Colquhoun H.M., Dudman C.C., O'Mahoney C.A., Robinson G.C., Williams D.J., Adv. Mater., 2, (1990)

[5]

LeBarny P., Dubois J.C., Side Chain Liquid Crystal Polymers, (1989)

[6]

Uchida S., Morita K., Miyoshi K., Hashimoto K., Kawasaki K., Mol. Cryst. Liq. Cryst., 155, (1988)

[7]

Suzuki T., Okawa T., Ohnuma T., Sahon Y., Die Makromolekulare Chemie, Rapid Communications, 9, (1988)

[8]

Scherowsky G., Schliwa A., Springer J., Kuhnpast K., Trapp W., Fast switching ferroelectric liquid-crystalline polymers, Liquid Crystals, 5, (1989)

[9]

Dumon M., Nguyen H.T., Mauzac M., Destrade C., Achard M.F., Gasparoux M., Macromolecules, 23, (1990)

[10]

Zentel R., Reckert G., Bualek S., Kapitza H., Makromol. Chem., 190, (1989)

← 1 2 3 →