(NBU4P)2[OS20(CO)40], A THERMOLYTICALLY GENERATED HIGH-NUCLEARITY CLUSTER WITH A TETRAHEDRAL CUBIC-CLOSE-PACKED METAL CORE

被引:43
作者
AMOROSO, AJ
GADE, LH
JOHNSON, BFG
LEWIS, J
RAITHBY, PR
WONG, WT
机构
[1] University Chemical Laboratory, Cambridge, CB2 1EW, Lensfield Road
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期
关键词
D O I
10.1002/anie.199101071
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A fully symmetrical osmium tetrahedron consisting of twenty cubic-close-packed metal atoms constitutes the framework of dianion 1. There is no evidence for interstitial carbon or hydrogen atoms in the framework. Moreover, the Os-Os distances approach those of elemental osmium. Cyclovoltammetric measurements indicate that 1 exhibits interesting electrochemical properties (see also the Highlight on p. 72).
引用
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页码:107 / 109
页数:3
相关论文
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