(NBU4P)2[OS20(CO)40], A THERMOLYTICALLY GENERATED HIGH-NUCLEARITY CLUSTER WITH A TETRAHEDRAL CUBIC-CLOSE-PACKED METAL CORE

被引：43

作者：

AMOROSO, AJ

GADE, LH

JOHNSON, BFG

LEWIS, J

RAITHBY, PR

WONG, WT

机构：

[1] University Chemical Laboratory, Cambridge, CB2 1EW, Lensfield Road

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期

关键词：

D O I：

10.1002/anie.199101071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fully symmetrical osmium tetrahedron consisting of twenty cubic-close-packed metal atoms constitutes the framework of dianion 1. There is no evidence for interstitial carbon or hydrogen atoms in the framework. Moreover, the Os-Os distances approach those of elemental osmium. Cyclovoltammetric measurements indicate that 1 exhibits interesting electrochemical properties (see also the Highlight on p. 72).

引用

页码：107 / 109

页数：3

共 24 条

[1] AMOROSO A, UNPUB
[2] BAILEY PJ, 1990, THESIS U CAMBRIDGE
[3] THE NOVEL ELECTROCHEMISTRY OF THE DECAOSMIUM CLUSTER [OS10C(CO)24]2-
BARLEY, MH
DRAKE, SR
JOHNSON, BFG
LEWIS, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) : 1657 - 1659
[4] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE ANALYSIS OF THE LARGEST BINARY OSMIUM CARBONYL CLUSTER - [OS17(CO)36]2-
CHARALAMBOUS, E
GADE, LH
JOHNSON, BFG
LEWIS, J
MCPARTLIN, M
POWELL, HR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (09) : 688 - 690
[5] CHINI P, 1980, J ORGANOMET CHEM, V200, P51
[6] PHYSICS OF METAL-CLUSTERS
COHEN, ML
CHOU, MY
KNIGHT, WD
DEHEER, WA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (12) : 3141 - 3149
[7] HIGH NUCLEARITY OSMIUM CLUSTER RADICALS
DRAKE, SR
JOHNSON, BFG
LEWIS, J
MCQUEEN, RCS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (05): : 1051 - 1054
[8] ERTL G, 1986, METAL CLUSTERS CATAL, P575
[9] Fantucci P., 1988, Elemental and Molecular Clusters. Proceedings of the 13th International School, P125
[10] BONDING CAPABILITIES OF NICKEL CLUSTER IONS - SYNTHETIC CHEMISTRY IN A MOLECULAR-BEAM
FAYET, P
MCGLINCHEY, MJ
WOSTE, LH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (06) : 1733 - 1738

← 1 2 3 →