FORMATION IN-SITU OF PERFLUOROALKYLATED FULLERENES

被引：15

作者：

FRITZ, HP

HIEMEYER, R

机构：

[1] Anorganisch-chemisches Institut der Technischen Universität München, D-85747 Garching b. München

来源：

CARBON | 1995年 / 33卷 / 11期

关键词：

FULLERENES; MASS SPECTROSCOPY; TRIFLUOROMETHYLATION;

D O I：

10.1016/0008-6223(95)00122-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mass spectrometric studies have shown that contact-are vaporization of polytetrafluoroethylene-containing graphite rods leads to the formation of mainly trifluoromethylated [60]-fullerenes of the general formula C-60(CF3)(n)H-m, where n = 1-8 and m = 0-9. Similar results were achieved by using sodium trifluoroacetate/graphite composite rods.

引用

收藏

页码：1601 / 1609

页数：9

相关论文

共 35 条

[1] ATOMS IN CARBON CAGES - THE STRUCTURE AND PROPERTIES OF ENDOHEDRAL FULLERENES [J].

BETHUNE, DS ;

JOHNSON, RD ;

SALEM, JR ;

DEVRIES, MS ;

YANNONI, CS .

NATURE, 1993, 366 (6451) :123-128

[2] REGIOCHEMISTRY OF RADICAL-ADDITION TO C-70 [J].

BORGHI, R ;

LUNAZZI, L ;

PLACUCCI, G ;

KRUSIC, PJ ;

DIXON, DA ;

KNIGHT, LB .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (21) :5395-5398

[3] LASER DESORPTION FOURIER-TRANSFORM MASS-SPECTRA OF POLY(PHENYLENE SULFIDE), POLYANILINE, POLYVINYL PHENOL), POLYPYRENE, AND RELATED OLIGOMERS - EVIDENCE FOR CARBON CLUSTERS AND FEASIBILITY OF PHYSICAL DIMENSION MEASUREMENT [J].

BROWN, CE ;

KOVACIC, P ;

WELCH, KJ ;

CODY, RB ;

HEIN, RE ;

KINSINGER, JA .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1988, 26 (01) :131-148

[4] EXPERIMENTAL STUDIES ON THE FORMATION PROCESS OF C-60 [J].

BROYER, M ;

GOERES, A ;

PELLARIN, M ;

SEDLMAYR, E ;

VIALLE, JL ;

WOSTE, L .

CHEMICAL PHYSICS LETTERS, 1992, 198 (1-2) :128-134

[5] STABILITY AND FRAGMENTATION OF CARBON CLUSTERS [J].

CAMPBELL, EEB ;

ULMER, G ;

BUSMANN, HG ;

HERTEL, IV .

CHEMICAL PHYSICS LETTERS, 1990, 175 (05) :505-510

[6] FULLERENES WITH METALS INSIDE [J].

CHAI, Y ;

GUO, T ;

JIN, CM ;

HAUFLER, RE ;

CHIBANTE, LPF ;

FURE, J ;

WANG, LH ;

ALFORD, JM ;

SMALLEY, RE .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20) :7564-7568

[7] ON THE MECHANISM OF FULLERENE FORMATION - TRAPPING OF SOME POSSIBLE INTERMEDIATES [J].

CHANG, TM ;

NAIM, A ;

AHMED, SN ;

GOODLOE, G ;

SHEVLIN, PB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (19) :7603-7604

[8] PHYSICAL AND CHEMICAL EVIDENCE FOR METALLOFULLERENES WITH METAL ATOMS AS PART OF THE CAGE [J].

CLEMMER, DE ;

HUNTER, JM ;

SHELIMOV, KB ;

JARROLD, MF .

NATURE, 1994, 372 (6503) :248-250

[9] X-RAY PHOTOELECTRON AND NMR-STUDIES OF POLYFLUORINATED C-60 - EVIDENCE THAT C-C BONDS ARE BROKEN [J].

COX, DM ;

CAMERON, SD ;

TUINMAN, A ;

GAKH, A ;

ADCOCK, JL ;

COMPTON, RN ;

HAGAMAN, EW ;

KNIAZ, K ;

FISCHER, JE ;

STRONGIN, RM ;

CICHY, MA ;

SMITH, AB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1115-1120

[10]

CRANE JR, UNPUB

← 1 2 3 4 →