SELECTIVE INCLUSION OF ETHANOL BY TRIPHENYLSILANOL - CRYSTAL-STRUCTURE AND THERMAL-ANALYSIS

被引：27

作者：

BOURNE, SA

NASSIMBENI, LR

SKOBRIDIS, K

WEBER, E

机构：

[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA

[2] UNIV BONN,INST ORGAN CHEM & BIOCHEM,W-5300 BONN 1,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 05期

关键词：

D O I：

10.1039/c39910000282

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triphenylsilanol is a selective host for ethanol in the presence of other simple homologous alcohols and forms a 4:1 coordinatoclathrate stabilised by hydrogen bonds; thermal decomposition takes place in a two-step process with the formation of a new intermediate phase.

引用

页码：282 / 283

页数：2

共 6 条

[1] BRAUN MA, COMMUNICATION
[2] SEPARATION OF ISOMERIC ALCOHOLS BY SELECTIVE COMPLEXATION WITH N,N,N',N'-TETRACYCLOHEXYLFUMARAMIDE AND N,N,N',N'-TETRAISOPROPYLFUMARAMIDE, AND STRUCTURES OF 2 RESULTING CRYSTALLINE ADDUCTS
TODA, F
TAGAMI, Y
MAK, TCW
[J]. CHEMISTRY LETTERS, 1986, (11) : 1909 - 1912
[3] TODA F, 1987, TOP CURR CHEM, V140, P43
[4] SPECIFIC ENTRAPMENT OF METHANOL AND DIMETHYL-SULFOXIDE (DMSO) BY A SIMPLE HOST COMPOUND (TRIPHENYLMETHANOL) - CRYSTAL-STRUCTURES OF THE PH3COH.MEOH (1-1) AND PH3COH.DMSO (2-1) CLATHRATE INCLUSION COMPLEXES
WEBER, E
SKOBRIDIS, K
GOLDBERG, I
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (17) : 1195 - 1197
[5] WEBER E, 1984, J AM CHEM SOC, V106, P3295
[6] Weber E., 1983, J INCLUSION PHENOM, V1, P79

← 1 →