PHOSPHINATION OF STYRENE-BROMOSTYRENE-DIVINYLBENZENE TERPOLYMERS

被引：3

作者：

BACQUET, M

LEMAGUER, D

CAZE, C

机构：

[1] Laboratoire de Chimie Macromoléculaire, UA, CNRS, Université des Sciences et Techniques de Lille, Villeneuve

[2] E. N. S. C. Lille, Villeneuve D'ascq, 59652

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1991年 / 190卷

关键词：

D O I：

10.1002/apmc.1991.051900107

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The phosphination of styrene-bromostyrene-divinylbenzene terpolymers as a function of their textural and chemical characteristics has been studied. A small decrease of both specific area and porous volume with phosphination was observed. Chemical analysis showed the presence of side reactions like reduction of the halogen, addition on the double bond, and crosslinking reaction involving the different functional groups. The phosphorous distribution was inhomogeneous; this was attributed to a difference of crosslinking density in the beads due to the particular morphology of this type of support.

引用

页码：99 / 109

页数：11

共 23 条

[1] INFLUENCE OF THE PREPARATION METHODS ON THE FUNCTIONAL-GROUP DISTRIBUTION OF CHLOROMETHYLATED STYRENE DIVINYL BENZENE COPOLYMERS [J].

ALAMI, SW ;

LEMAGUER, D ;

CAZE, C .

REACTIVE POLYMERS, 1987, 6 (2-3) :213-219

[2] POROUS TEXTURE AND BROMINE DISTRIBUTION IN POROUS STYRENE BROMOSTYRENE DIVINYLBENZENE TERPOLYMERS [J].

BACQUET, M ;

LEMAGUER, D ;

CAZE, C .

EUROPEAN POLYMER JOURNAL, 1988, 24 (06) :533-537

[3] SPATIAL-DISTRIBUTION OF PENDENT VINYL GROUPS DURING CHLOROMETHYLATION OF MACROPOROUS STYRENE DIVINYLBENZENE COPOLYMERS [J].

BACQUET, M ;

CAZE, C ;

LAUREYNS, J ;

BREMARD, C .

REACTIVE POLYMERS, 1988, 9 (02) :147-153

[4]

BACQUET M, UNPUB REACT POLYM IO

[5] Adsorption of gases in multimolecular layers [J].

Brunauer, S ;

Emmett, PH ;

Teller, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319

[6]

CARLU JC, UNPUB REACT POLYM IO

[7]

CAZE C, UNPUB REACT POLYM IO

[8]

DUSEK K, 1973, J POLYM SCI POLYM S, V42, P713

[9] SYNTHETIC AND CATALYTIC STUDIES OF POLYMER-BOUND METAL-CARBONYLS [J].

EVANS, GO ;

PITTMAN, CU ;

MCMILLAN, R ;

BEACH, RT ;

JONES, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 67 (02) :295-314

[10] PREPARATION OF POLYMERIC ORGANOPHOSPHORUS LIGANDS FOR CATALYST ATTACHMENT [J].

GRUBBS, RH ;

SU, SCH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 122 (02) :151-157

← 1 2 3 →