CRYSTAL-STRUCTURE OF THE ADDUCT OF THIOUREA WITH 2,6-DIETHYLNAPHTHALENE

被引：10

作者：

SHINDO, T ^{[1
]}

SHINDO, M ^{[1
]}

OHNUMA, H ^{[1
]}

KABUTO, C ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC PHARMACEUT SCI, INSTRUMENTAL ANAL CTR CHEM, SENDAI, MIYAGI 980, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 07期

关键词：

D O I：

10.1246/bcsj.66.1914

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of 2,6-diethylnaphthalene thiourea adduct was solved by single crystal X-ray diffraction method. The crystal is monoclinic, space group P2(1)/c, with a = 12.571(3), b = 9.282(2), c = 14.634(3) angstrom, beta = 92.14 (2)degrees, V = 1706.3(6) angstrom3 and Z = 2. The final R value was 0.083. The structure was composed of thiourea (host) molecules enclosing channels with hexagonal-prism and 2,6-diethylnaphthalene (guest) molecules in the channels. The cross-section of the channel was deformed hexagon. In the channel, the occupying channel length of the guest molecule was 12.571(3) angstrom.

引用

页码：1914 / 1918

页数：5

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