CONFORMATION OF ALKANETHIOLS ON AU, AG(111), AND PT(111) ELECTRODES - A VIBRATIONAL SPECTROSCOPY STUDY

被引：97

作者：

HINES, MA ^{[1
]}

TODD, JA ^{[1
]}

GUYOTSIONNEST, P ^{[1
]}

机构：

[1] UNIV CHICAGO,JAMES FRANCK INST,CHICAGO,IL 60637

来源：

LANGMUIR | 1995年 / 11卷 / 02期

关键词：

D O I：

10.1021/la00002a022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical effects on self-assembled monolayers of alkanethiols, CnH2n divided by 1SH (n = 9, 10, 18), on Au, Ag(111), and Pt(111) are investigated using sum-frequency generation. Layers on Au and Ag(111) show no noticeable effects. Layers on Pt(111) show gauche transformations that are reversibly eliminated at negative or positive potentials.

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页码：493 / 497

页数：5

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