CYCLIC VOLTAMMETRY FOR ASSISTED ION TRANSFER AT AN ITIES

被引：42

作者：

BEATTIE, PD

WILLINGTON, RG

GIRAULT, HH

机构：

[1] Department of Chemistry, University of Edinburgh, Edinburgh, EH9 3JJ, West Mains Road

[2] Laboratoire d'Electrochimie, Ecole Polytechnique Fédérale de Lausanne

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1995年 / 396卷 / 1-2期

关键词：

NUMERICAL METHODS; MATHEMATICAL MODEL; CYCLIC VOLTAMMETRY; ASSISTED ION TRANSFER; ITIES;

D O I：

10.1016/0022-0728(94)03734-K

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A general numerical method to model linear sweep voltammetry for assisted ion transfer reactions of 1:1 stoichiometry is presented. The approach is based on a Nicholson-Shain integration of the convolution integrals. This numerical approach is validated by simulations using the hopscotch algorithm. Experimental results corroborate the calculations.

引用

收藏

页码：317 / 323

页数：7

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