STEREOSELECTIVE SYNTHESIS OF BETA-PHENYLSERINE FROM GLYCINE AND BENZALDEHYDE AS MEDIATED BY CATALYTIC BILAYER-MEMBRANES, ARTIFICIAL VITAMIN-B6-DEPENDENT ENZYMES

被引：14

作者：

KIKUCHI, J ^{[1
]}

TAKASHIMA, T ^{[1
]}

NAKAO, H ^{[1
]}

HIE, K ^{[1
]}

ETOH, H ^{[1
]}

NOGUCHI, Y ^{[1
]}

SUEHIRO, K ^{[1
]}

MURAKAMI, Y ^{[1
]}

机构：

[1] KYUSHU UNIV, FAC ENGN, DEPT CHEM SCI & TECHNOL, HIGASHI KU, FUKUOKA 812, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.553

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aldolation of glycine with benzaldehyde to yield beta-phenylserine was catalyzed by supramolecular assemblies formed with a synthetic peptide lipid, a hydrophobic vitamin B6 derivative, and zinc(II) ions in aqueous media under mild conditions. A diastereomeric ratio of the reaction products was much dependent on a size and a phase property of the vesicular catalyst.

引用

页码：553 / 556

页数：4

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