TUNGSTEN DISULFIDE PREPARED FROM AMMONIUM TETRATHIOTUNGSTATE AS A CATALYST WITH HIGH-PERFORMANCE FOR THE SELECTIVE HYDROGENATION OF CO2 TO CO

被引：9

作者：

OSAKI, T

TAODA, H

HORIUCHI, T

YAMAKITA, H

机构：

[1] Government Industrial Research Institute, Nagoya, 462, Nagoya Hirate-cho, Kita-ku

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1993年 / 51卷 / 01期

关键词：

D O I：

10.1007/BF02062475

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For the hydrogenation of CO2 to CO, tungsten disulfide prepared by decomposing ammonium tetrathiotungstate,was found to exhibit high activity and good selectivity (> 99.9%). Large surface area, viz., 64 m2 g-1, is primarily responsible for the high activity, while the lack of activity in Co methanation for the good selectivity.

引用

页码：39 / 43

页数：5

共 7 条

[1] KINETICS, ISOTOPE EFFECTS, AND MECHANISM FOR THE HYDROGENATION OF CARBON-MONOXIDE ON SUPPORTED NICKEL-CATALYSTS [J].